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10.1 Free Radical Halogenation | Organic Chemistry

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Chads Prep

Chad summarizes the three free radical halogenation reactions: chlorination, bromination, and allylic or benzylic bromination with NBS. He explains the selectivity associated with bromination reactions and how to calculate the relative amounts of products formed in free radical chlorination and bromination reactions. He then covers allylic bromination and benzylic bromination using Nbromosuccinimide (NBS). Finally, Chad concludes the lessons by providing an example of how to determine the number of monochlorination products for a reactant.

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00:00 Lesson Introduction
00:50 Free Radical Chlorination (Cl2 / hv) vs Bromination (Br2 / hv)
03:15 Allylic / Benzylic Bromination with NBS (Nbromosuccinimide)
04:36 How to Calculate Relative Amounts of Chlorination and Bromination Products
11:16 How to Determine the Number of Monochlorination or Monobromination Products

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