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16.6 Cycloaddition Reactions | Organic Chemistry

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Chads Prep

Chad builds upon the last lesson on DielsAlder reactions to comprehensively cover Cycloaddition Reaction in general. He starts with a review of the DielsAlder reaction and shows the difference between when it is performed under thermal vs photochemical conditions. He also shows when suprafacialsuprafacial vs suprafacialantarafacial relationships between diene and dienophile are allowed and forbidden and the resulting stereochemistry associated with each. Finally, Chad also covers examples 6 + 2 and 2 + 2 cycloadditions under both thermal and photochemical conditions.

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00:00 Lesson Introduction
00:54 Review of FMO Theory and DielsAlder Thermal Conditions
05:43 4 + 2 Cycloaddition Under Photochemical Conditions
10:19 Suprafacial vs Antarafacial; Effect on Stereochemistry
19:45 6 + 2 Cycloadditions
24:36 2 +2 Cycloadditions

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posted by kursenax