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Introduction to Electrochemical Impedance Spectroscopy (EIS: Maths and Theory)

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Sam Cooper

Lecture deliver as part of a series from the Electrochemistry Network for graduates at Imperial College London (17/02/2021).

Dr Sam Cooper https://www.imperial.ac.uk/people/sam...

If you enjoy this style of teaching, try my Mathematics for Machine Learning specialization on Coursera:
https://www.coursera.org/specializati...

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Slides: https://www.dropbox.com/s/2dxnssou0gz...

00:00 Introduction
01:53 Linearity
04:23 The classic idealised components: L, R and C
07:49 Hydraulic & mechanical analogies for circuits
16:59 Scenario #1 : Just a resistor
19:12 Scenario #2 : Just a capacitor (take 1)
21:28 The big muddle and Fourier transform
27:00 Scenario #2 : Just a capacitor (take 2)
30:21 Scenario #2 : Just a capacitor (take 3)
33:09 Scenario #3 : R and C in series
36:02 Convenient representation
38:31 Parallel circuits
41:59 Scenario #4 : R and C in parallel
46:49 Question on potentiostats
51:32 Nyquist plots
54:14 Nyquist plot of a resistor
55:48 Nyquist plot of a capacitor
58:29 Nyquist plot of an inductor
59:45 Nyquist plot of series RC
1:04:12 Nyquist plot of parallel RC
1:13:25 The simplest complicated system
1:23:12 The simplest complicated system animation!
1:24:41 Constant Phase Elements (CPEs)
1:32:33 Distribution of relaxation times (DRT)
1:33:57 Warburg and DRT equivalence to infinite series
1:35:59 Gerischer elements
1:36:50 Simple equivalences of parallel RC to R or C
1:38:31 My research #1 : Diffusion impedance
1:39:57 My research #2 : The electrode tortuosity factor
1:40:38 Copper or "copper"?
1:40:59 Symmetrical cells are tricky!
1:41:43 Goodbye :)

posted by nhaguga