The people of twitter hath spoken, I present ye with a guide/playthrough for establishing relays at Kerbin, Minmus and Mun in 1 launch, with the Kerbin and Minmus ones being synchronous (aka "geostationary" though that term technically only applies to Earth)

Twitter............................►  / matt_lowne  
Patreon...........................►https://goo.gl/lLDt79
Discord............................►  / discord  
Second channel..............►https://goo.gl/cww3Ik

Mods:
Gameplay: Kerbal Engineer Redux; Better Time Warp; Camera Tools

Synchronous orbit calculator:
http://www.skyrender.net/ksp_sync_cal...